ph adjusters

Citric Acid

Citrus Peel

ph adjusterchelating agentantioxidantpreservative
CAS Number:77-92-9

INCI Name

Citric Acid

Functions

4 Roles

Sustainability

9/10

Category

ph adjusters

What It Does

Citric Acid is an alpha-hydroxy acid (AHA) naturally found in citrus fruits but commercially produced through fermentation of sugar substrates by Aspergillus niger mold. In cosmetics, it serves as a multifunctional workhorse ingredient, primarily used to adjust and buffer pH to optimal ranges for product stability and skin compatibility, while also chelating metal ions that could otherwise catalyze oxidation and degradation. Formulators favor it for its excellent solubility, clean label appeal, and ability to enhance preservative efficacy while providing mild antioxidant benefits at concentrations typically ranging from 0.01-2%.

Optimizes formula stability
Ensures skin compatibility
Maximizes ingredient efficacy
Prevents irritation

Technical Properties

pH Range

2.2-3.5

Optimal working range

Ionic Charge

anionic

Molecular charge type

Viscosity Effect

neutral

Impact on formula thickness

Ingredient Compatibility

Known Interactions

CASEINIncompatiblePrecipitation

Casein precipitates at pH < 4.6. Citric acid beverages will cause immediate, irreversible curdling. Use plant protein or hydrolyzed whey for acidic drinks.

PROBIOTICSUse CautionDegradation

High concentrations of Citric Acid (pH < 3.5) can kill acid-sensitive probiotic strains (Lactobacillus, Bifidobacterium) during shelf life. Use acid-resistant strains or enteric coating if combining.

WHEY PROTEINUse CautionPrecipitation

Whey protein denatures and precipitates below pH 4.6 (its isoelectric point). Citric acid-based beverages at pH 3-4 will cause visible protein aggregation. Use hydrolyzed whey or plant protein for acidic beverages.

CALCIUMNotePrecipitation

High Calcium + Citric Acid can form calcium citrate precipitate in beverages, causing cloudiness or sedimentation. Manageable with proper formulation (sequestrants, pH control), but test stability.

Compatibility analysis powered by OpenMix — open-source formulation science

Sustainability Profile

Sustainability Score

9/10

Biodegradability

readily biodegradable

Source

fermentation

Feedstock

corn or sugar-based carbohydrates

Quick Reference

Full INCI Name
Citric Acid
Common Name
Citrus Peel
CAS Number
77-92-9
Category
ph adjusters

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